Recherches sur la Conductibilité Galvanique des Électrolytes. I: La conductibilté des solutions aqueuses extrêmement diluées déterminée au moyen du dépolarisateur. II: Théorie chimique des électrolytes.

Stockholm: P.A. Norstedt, 1884. First edition.

The rare offprint issue of Arrhenius’s landmark discovery of the theory of electrolytic disassociation. Arrhenius was awarded the 1903 Nobel Prize in chemistry “in recognition of the extraordinary services he has rendered to the advancement of chemistry by his electrolytic theory of dissociation.”

By 1880, “it was known that solutions of certain compounds conduct electricity and that chemical reactions could occur when a current was passed. It was thought that the current decomposed the substance. In 1883 Arrhenius proposed a theory that substances were partly converted into an active form when dissolved. The active part was responsible for conductivity. In the case of acids and bases, he correlated the strength with the degree of decomposition on solution. This work was published as Reserches sur la conductibilite galvanique des electrolytes (1884; Researches on the Electrical Conductivity of Electrolytes) and submitted as his doctoral dissertation... Arrhenius sent his work to several leading physical chemists, including Jacobus van't Hoff. Friedrich Ostwald, and Rudolf Clausius, who were immediately impressed” (Biographical Encyclopedia of Scientists). Arrhenius soon gained high international acclaim, ultimately being awarded the 1903 Nobel Prize in chemistry for his work.

8vo: 225 x 145 mm. Original printed wrappers, uncut and unopened, a very fine and completely unmarked copy, pp. [2], [1-3] 4-63 [1:blank] and 1 lithographed plate; [1-3] 4-89 [1:blank]. Rare.

Item #3160

Price: $1,850.00

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